Fluorine Oxidation Number


We are going to look at some examples from vanadium chemistry. If you don't know anything about vanadium, it doesn't matter in the slightest.

Vanadium forms a number of different ions - for example, V2+ and V3+. If you think about how these might be produced from vanadium metal, the 2+ ion will be formed by oxidising the metal by removing two electrons:

The vanadium is now said to be in an oxidation state of +2.

  • Fluorine's oxidation number is -1.In an ion, the oxidation number is equal to its charge. Above 200 °C, OF 2 decomposes to oxygen and fluorine via a radical mechanism. So that's the reason why oxygen has a +2 oxidation state in OF2. When iodine forms a compound with a.
  • Elements in periodic group IA have oxidation numbers of +1, and elements in periodic group IIA have oxidation numbers of +2, e.g., Na +. The most electronegative element, fluorine, is always assigned both electrons from any bond in which it participates. This gives fluorine an oxidation number of –1 in all its compounds, e.g., OF 2.

VALENCE/OXIDATION NUMBERS Element/Ion/Radical Symbol Valence/Oxidation Number Aluminum Al 3+ Antimony Sb 3+, 5+ Arsenic As 3+, 5+ Barium Ba 2+ Bismuth Bi 3+ Boron B 3+ Bromine Br 1- Calcium Ca 2+ Cadmium Cd 2+ Carbon C 2+, 4+ Chlorine Cl 1- Chromium Cr 2+, 3+, 6+ Cobalt Co 2+, 3+ Copper Cu 1+, 2+ Fluorine F 1- Hydrogen H 1+ Iodine I 1- Iron Fe.

Oxidation Number Of Fluorine In F2

Removal of another electron gives the V3+ ion:

What Is Fluorine Oxidation Number

The vanadium now has an oxidation state of +3.

Removal of another electron gives a more unusual looking ion, VO2+.

The vanadium is now in an oxidation state of +4. Notice that the oxidation state isn't simply counting the charge on the ion (that was true for the first two cases but not for this one).

The positive oxidation state is counting the total number of electrons which have had to be removed - starting from the element.

It is also possible to remove a fifth electron to give another ion (easily confused with the one before!). The oxidation state of the vanadium is now +5.

Oxidation number fluorine have

Every time you oxidise the vanadium by removing another electron from it, its oxidation state increases by 1.

Fairly obviously, if you start adding electrons again the oxidation state will fall. You could eventually get back to the element vanadium which would have an oxidation state of zero.

Fluorine Oxidation Number

What if you kept on adding electrons to the element? You can't actually do that with vanadium, but you can with an element like sulphur.

The sulphur has an oxidation state of -2.


Oxidation state shows the total number of electrons which have been removed from an element (a positive oxidation state) or added to an element (a negative oxidation state) to get to its present state.

Oxidation involves an increase in oxidation state

Oxidation Number Fluorine Have

Reduction involves a decrease in oxidation state

Recognising this simple pattern is the single most important thing about the concept of oxidation states. If you know how the oxidation state of an element changes during a reaction, you can instantly tell whether it is being oxidised or reduced without having to work in terms of electron-half-equations and electron transfers.

Working out oxidation states

Why Is Fluorine Oxidation Number Always Negative

Can i read ebooks on my macbook pro. You don't work out oxidation states by counting the numbers of electrons transferred. It would take far too long. Instead you learn some simple rules, and do some very simple sums!